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Benzene’s forgotten isomer takes centre stage in organic synthesis An overlooked benzene isomer could become a powerful and versatile reagent in organic synthesis.Researchers demonstrated that the high energy compound 1,2,3-cyclohexatriene readily participates in a diverse range of cycloaddition, nucleophilic addition and σ-bond insertion reactions, enabling chemists to construct complex molecular architectures in just a few steps. Isomers of benzene have captured the imagination of organic chemists for decades and studies of unusual strained structures such as Dewar-benzene and prismane have proven pivotal to our understanding of resonance theory and aromaticity. High-energy relatives of benzene like benzyne and 1,2-cyclohexadiene have likewise attracted significant interest, their propensity to undergo strain-promoted reactions making them valuable synthetic intermediates. Surprisingly, 1,2,3-cyclohexatriene has not received the same degree of attention. Unlike the alternating conjug...

 

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  The Spark Within: Previously Unknown Intracellular Electricity May Power Biology In a groundbreaking study, researchers have uncovered electrical activity in biological condensates, cellular structures that were previously not known to harbor such activity. Traditionally, scientists believed that electrical imbalances, crucial for biological processes, could only exist across cellular membranes. However, this study, building on previous research that found such imbalances could occur between air and water microdroplets, reveals that similar electrical fields also exist within and around biological condensates. The researchers discovered that these imbalances could spark reactive oxygen or “redox” reactions. The finding not only challenges existing understanding of biological chemistry but could also provide insights into how the first life on Earth harnessed the energy necessary for its existence. The human body relies heavily on electrical charges. Lightning-like pulses of energ...